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Understanding the degradation mechanisms of catalysts during use is critical to improving catalyst durability. Using Hummingbird Scientific’s in-situ TEM gas-heating sample holder, researchers at the University of Illinois at Chicago, the University of Pittsburgh and Argonne National Laboratory have studied sintering behavior of Pt, and Au-core Pt-shell nanoparticles on 2D MoS2 supports at high temperatures under vacuum, nitrogen, hydrogen, and in air environments.
Based on their in-situ TEM observations, they concluded the following:
- Environmental: Particle migration and coalescence was the main mechanism that led to Pt and Au/Pt nanoparticles degradation under vacuum, nitrogen, and hydrogen environments. In air, the degradation of the MoS2 substrate was also present. Pt was less stable in hydrogen when compared with the Pt nanoparticles under vacuum or nitrogen. It is posed that this could be due to Pt−H interactions that weakened the adhesion of Pt to the MoS2 surface.
- Composition: In hydrogen, the stability of Au/Pt was higher in comparison to Pt nanoparticles. It is posed that this is caused by hydrogen promoting alloying of Pt/Au, thus reducing the number of Pt at the surface and increasing the number of Pt atoms in contact with the MoS2 substrate.
- Size: Alloying promoted by the presence of H2 was more pronounced in small size Au/Pt NPs, which resulted in a higher sintering resistance when compared to larger Au/Pt and Pt nanoparticles.
Their work provides vital insights into what affects catalyst degradation mechanisms on 2D catalyst supports. They published their work in ACS Nano.
